maxwell Relations My topic for the report is Thermodynamics maxwell Relations, and in this report I will show how to derive the Maxwell Relations, as well as give several examples of how and when they atomic number 18 supposed to used. The change in U depend on the changes in the body entropy, volume and XIs this intellection may be abbreviation (1-1) U = U(S, V, XI) In system of constant mass and composition, whose work derriere be denotative precisely in terms of its PV properties, in that location are no Xs and U is changed only by bilateral heat and P dV work. Therefore (1-2) dU = T dS P dV. The differential of the accumulated internal expertness in a fixed-composition, P dV work system is.
= dH = dU + d(PV) (1-3) = dU + P dV + V dP. replace equation (1-2) in equation (1-3), we hold (1-4) dH = T dS + V dP. From the defining the Helmholtz function A we obtain ( 1-5) dA = dU d(TS) = dU T ...
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